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Science — CBSE Class 10 board question

Q1. [5]
A carbon compound 'A' is widely used as a preservative in pickles and has a molecular formula C₂H₄O₂. This compound reacts with ethanol to form a sweet smelling compound 'B'.
  1. (i) Identify the compound 'A' and write its structure.
  2. (ii) Write the chemical equation for the reaction of 'A' with ethanol to form compound 'B'. State the role of presence of an acid in the reaction.
  3. (iii) How can we get compound 'A' back from 'B' ?
  4. (iv) How can 'A' be obtained from ethanol ?
  5. (v) Name the gas produced when compound 'A' reacts with washing soda.
Previously asked in CBSE board exam
2025 31/4/1 Q34(B)
Generated by claude-sonnet-4-6 · 2026-06-15 06:49 · grounding rag
Model Answer

Compound 'A' is Ethanoic acid (CH₃COOH).

(i) Ethanoic acid; molecular formula C₂H₄O₂.

Structure:

$$\text{CH}_3 - \text{COOH}$$

(Carbon–carbon single bond, with —COOH as the carboxylic acid functional group.)

(ii) Chemical equation for esterification:

$$\text{CH}_3\text{COOH} + \text{C}_2\text{H}_5\text{OH} \xrightarrow{\text{conc. H}_2\text{SO}_4, \Delta} \text{CH}_3\text{COOC}_2\text{H}_5 + \text{H}_2\text{O}$$

Compound 'B' is ethyl ethanoate (an ester). Concentrated H₂SO₄ acts as a catalyst (and dehydrating agent), speeding up the reaction.

(iii) Compound 'A' (ethanoic acid) can be obtained back from 'B' by saponification — heating the ester 'B' with an acid (or alkali) and water (hydrolysis).

(iv) Ethanoic acid is obtained from ethanol by oxidation, using an oxidising agent such as alkaline KMnO₄ or acidified K₂Cr₂O₇.

$$\text{C}_2\text{H}_5\text{OH} \xrightarrow{[\text{O}]} \text{CH}_3\text{COOH}$$

(v) Carbon dioxide (CO₂) gas is produced when ethanoic acid reacts with washing soda (Na₂CO₃).

$$2\text{CH}_3\text{COOH} + \text{Na}_2\text{CO}_3 \rightarrow 2\text{CH}_3\text{COONa} + \text{H}_2\text{O} + \text{CO}_2\uparrow$$

Source: Chapter 4, Section 4.4 — Some Important Carbon Compounds: Ethanol and Ethanoic Acid

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Explanation
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