Option D is not true.
The correct identity is $\sec^2\theta - \tan^2\theta = 1$, so $\tan^2\theta - \sec^2\theta = -1$, not 1.
Source: Chapter 8, Section 8.5 Summary
The three Pythagorean identities are: $\sin^2A + \cos^2A = 1$; $\sec^2A - \tan^2A = 1$; $\cosec^2A - \cot^2A = 1$. Option D reverses the correct identity, making it wrong. Options A, B, C can be verified using basic ratio definitions and are all true.